Thermodynamics熱力學
Chapters章節  /  01 Property01 性質

Reading Property Tables讀取性質表

The interactives on this site compute properties for you — but homework, exams, and real engineering run on tables. This chapter is the practical skill: finding a state in the steam and refrigerant tables, interpolating between rows, and using the ideal-gas and gas-constant tables.本站的互動工具可為你計算性質——但作業、考試與實際工程却經常需要查。本章訓練實用技能:在蒸汽表與冷媒表中定位狀態、插値,以及使用理想氣體表與氣體常數表。

Interpolation trainer Steam · R-134a · air
Property · Overview性質·總覽

What you'll be able to do本章學習成果

  • Navigate saturation, superheated, and compressed-liquid tables.查閱飽和表、過熱蒸氣表與壓縮液體表
  • Interpolate linearly between table entries.在表格項目之間進行線性插値
  • Use quality for two-phase states and the ideal-gas tables for air.對兩相狀態使用乾度,對空氣使用理想氣體表
  • Look up the gas constant $R = R_u/M$ for common gases.查得常見氣體的氣體常數 $R = R_u/M$。

Key relations關鍵公式

Linear interpolation線性插値
$y = y_1 + (y_2-y_1)\dfrac{x-x_1}{x_2-x_1}$
Two-phase value兩相值
$y = y_f + x\,y_{fg}$
Gas constant氣體常數
$R = R_u/M$
Universal constant通用氣體常數
$R_u = 8.314$ kJ/kmol·K
Motivation動機

Why tables?為何查表?

For most real substances, the relationships among properties are too complex for a single equation. Measured values are compiled into tables — the steam tables for water, separate tables for each refrigerant, and ideal-gas tables for air. Correct table reading is a core engineering skill.對於大多數實際物質,各性質間的關係難以單一方程式描述。因此量測值被編成表格——水的蒸汽表、各冷媒專用表、空氣的理想氣體表。正確查表是工程师的核心學能。

Structure表格結構

Anatomy of the tables表格結構詳解

A typical substance comes with several tables:一般物質有多種表格:

  • Saturation tables — indexed by T and by p. List saturated-liquid (f) and saturated-vapor (g) properties plus vaporization change (fg). Use inside the dome.飽和表——分別以 T 與 p 為索引。列出飽和液 (f)、飽和蒸氣 (g) 與永魔變化量 (fg)。用於圓頂內部。
  • Superheated-vapor tables — right of the dome, where T and p are independent. List $v, u, h, s$.過熱蒸氣表——圓頂右側,T 與 p 獨立。列出 $v, u, h, s$。
  • Compressed-liquid tables — often approximated by $y(T,p) \approx y_f(T)$.壓縮液體表——常以 $y(T,p) \approx y_f(T)$ 近似。

Each table uses a reference state — only changes in $u$, $h$, $s$ matter.每個表以一個參考狀態為基準——只有 $u$、$h$、$s$ 的變化量才有意義。

Inside the dome圓頂內部

Two-phase states: quality兩相狀態:乾度

In the two-phase region $T$ and $p$ are not independent, so you need the quality $x$. Any property is the lever-rule blend:在兩相區中,$T$ 與 $p$ 並非獨立,因此需要乾度 $x$。任何性質的桿桿法則展開:

$$ y = y_f + x\,(y_g - y_f) = y_f + x\,y_{fg} $$
v, u, h, or s

(See Properties of Pure Substances for the full treatment.)(詳見純物質性質。)

The key skill核心技能

Linear interpolation線性插値

When your state falls between two rows, estimate by linear interpolation:當狀態介於兩行之間時,以線性插値估算性質:

$$ y = y_1 + (y_2 - y_1)\,\frac{x - x_1}{x_2 - x_1} $$
between rows 1 and 2

The same idea extends to double interpolation (both T and p).同樣思路可延伸至雙重插値(同時對 T 與 p)。

Interactive互動

Interpolation trainer插値練習器

A real saturated-water excerpt. Slide the target temperature: bracketing rows highlight and interpolation is worked out. Try 55 °C.實際飽和水表節選。滑動目標溫度:對應行將被標示,插値過程展開。嘗試 55 °C。

Representative steam-table values, abridged for practice. Real tables have finer spacing and more columns.

Gases氣體

Ideal-gas tables理想氣體表

For ideal gases, $u$ and $h$ depend on temperature only, so a table indexed by $T$ gives $u(T)$, $h(T)$, and the entropy function $s^\circ(T)$. A short air excerpt:對理想氣體,$u$ 與 $h$ 僅與溫度有關,以 $T$ 為索引的表即可給出 $u(T)$、$h(T)$ 與 $s^\circ(T)$。空氣節選:

T (K)h (kJ/kg)u (kJ/kg)s° (kJ/kg·K)
300300.19214.071.70203
400400.98286.161.99194
500503.02359.492.21952
10001046.04758.942.96770
15001635.971205.413.44516

Use $\Delta h = h(T_2) - h(T_1)$ directly. Entropy: $s_2 - s_1 = s^\circ_2 - s^\circ_1 - R\ln(p_2/p_1)$.直接使用 $\Delta h = h(T_2) - h(T_1)$。熵變化:$s_2 - s_1 = s^\circ_2 - s^\circ_1 - R\ln(p_2/p_1)$。

Reference參考表

Gas constants氣體常數

Each gas has its own $R = R_u/M$, with $R_u = 8.314$ kJ/kmol·K:每一氣體各有其常數 $R = R_u/M$,$R_u = 8.314$ kJ/kmol·K:

GasM (kg/kmol)R (kJ/kg·K)c_p (kJ/kg·K)k
Air28.970.28701.0051.40
Nitrogen (N₂)28.010.29681.0391.40
Oxygen (O₂)32.000.25980.9181.40
Carbon dioxide (CO₂)44.010.18890.8461.29
Water vapor (H₂O)18.020.46151.8641.33
Helium (He)4.0032.07695.1931.67
Worked example範例

Putting it together綜合應用

Example範例 Interpolating the steam table蒸汽表插値

Given: saturated water vapor at 55 °C. $h_g(50°\mathrm{C})=2592.1$ and $h_g(60°\mathrm{C})=2609.6$ kJ/kg.已知:55 °C 的飽和水蒸氣。$h_g(50°\mathrm{C})=2592.1$,$h_g(60°\mathrm{C})=2609.6$ kJ/kg。

Find: $h_g$ at 55 °C.求:55 °C 的 $h_g$。

Solution. 55 °C is halfway between the rows: $$h_g = 2592.1 + (2609.6-2592.1)\frac{55-50}{60-50} = 2600.9\ \tfrac{\text{kJ}}{\text{kg}}$$解:55 °C 在兩行正中間:$$h_g = 2592.1 + (2609.6-2592.1)\frac{55-50}{60-50} = 2600.9\ \tfrac{\text{kJ}}{\text{kg}}$$