What you'll be able to do本章學習成果
- Navigate saturation, superheated, and compressed-liquid tables.查閱飽和表、過熱蒸氣表與壓縮液體表。
- Interpolate linearly between table entries.在表格項目之間進行線性插値。
- Use quality for two-phase states and the ideal-gas tables for air.對兩相狀態使用乾度,對空氣使用理想氣體表。
- Look up the gas constant $R = R_u/M$ for common gases.查得常見氣體的氣體常數 $R = R_u/M$。
Key relations關鍵公式
Why tables?為何查表?
For most real substances, the relationships among properties are too complex for a single equation. Measured values are compiled into tables — the steam tables for water, separate tables for each refrigerant, and ideal-gas tables for air. Correct table reading is a core engineering skill.對於大多數實際物質,各性質間的關係難以單一方程式描述。因此量測值被編成表格——水的蒸汽表、各冷媒專用表、空氣的理想氣體表。正確查表是工程师的核心學能。
Anatomy of the tables表格結構詳解
A typical substance comes with several tables:一般物質有多種表格:
- Saturation tables — indexed by T and by p. List saturated-liquid (f) and saturated-vapor (g) properties plus vaporization change (fg). Use inside the dome.飽和表——分別以 T 與 p 為索引。列出飽和液 (f)、飽和蒸氣 (g) 與永魔變化量 (fg)。用於圓頂內部。
- Superheated-vapor tables — right of the dome, where T and p are independent. List $v, u, h, s$.過熱蒸氣表——圓頂右側,T 與 p 獨立。列出 $v, u, h, s$。
- Compressed-liquid tables — often approximated by $y(T,p) \approx y_f(T)$.壓縮液體表——常以 $y(T,p) \approx y_f(T)$ 近似。
Each table uses a reference state — only changes in $u$, $h$, $s$ matter.每個表以一個參考狀態為基準——只有 $u$、$h$、$s$ 的變化量才有意義。
Two-phase states: quality兩相狀態:乾度
In the two-phase region $T$ and $p$ are not independent, so you need the quality $x$. Any property is the lever-rule blend:在兩相區中,$T$ 與 $p$ 並非獨立,因此需要乾度 $x$。任何性質的桿桿法則展開:
(See Properties of Pure Substances for the full treatment.)(詳見純物質性質。)
Linear interpolation線性插値
When your state falls between two rows, estimate by linear interpolation:當狀態介於兩行之間時,以線性插値估算性質:
The same idea extends to double interpolation (both T and p).同樣思路可延伸至雙重插値(同時對 T 與 p)。
Interpolation trainer插値練習器
A real saturated-water excerpt. Slide the target temperature: bracketing rows highlight and interpolation is worked out. Try 55 °C.實際飽和水表節選。滑動目標溫度:對應行將被標示,插値過程展開。嘗試 55 °C。
Representative steam-table values, abridged for practice. Real tables have finer spacing and more columns.
Ideal-gas tables理想氣體表
For ideal gases, $u$ and $h$ depend on temperature only, so a table indexed by $T$ gives $u(T)$, $h(T)$, and the entropy function $s^\circ(T)$. A short air excerpt:對理想氣體,$u$ 與 $h$ 僅與溫度有關,以 $T$ 為索引的表即可給出 $u(T)$、$h(T)$ 與 $s^\circ(T)$。空氣節選:
| T (K) | h (kJ/kg) | u (kJ/kg) | s° (kJ/kg·K) |
|---|---|---|---|
| 300 | 300.19 | 214.07 | 1.70203 |
| 400 | 400.98 | 286.16 | 1.99194 |
| 500 | 503.02 | 359.49 | 2.21952 |
| 1000 | 1046.04 | 758.94 | 2.96770 |
| 1500 | 1635.97 | 1205.41 | 3.44516 |
Use $\Delta h = h(T_2) - h(T_1)$ directly. Entropy: $s_2 - s_1 = s^\circ_2 - s^\circ_1 - R\ln(p_2/p_1)$.直接使用 $\Delta h = h(T_2) - h(T_1)$。熵變化:$s_2 - s_1 = s^\circ_2 - s^\circ_1 - R\ln(p_2/p_1)$。
Gas constants氣體常數
Each gas has its own $R = R_u/M$, with $R_u = 8.314$ kJ/kmol·K:每一氣體各有其常數 $R = R_u/M$,$R_u = 8.314$ kJ/kmol·K:
| Gas | M (kg/kmol) | R (kJ/kg·K) | c_p (kJ/kg·K) | k |
|---|---|---|---|---|
| Air | 28.97 | 0.2870 | 1.005 | 1.40 |
| Nitrogen (N₂) | 28.01 | 0.2968 | 1.039 | 1.40 |
| Oxygen (O₂) | 32.00 | 0.2598 | 0.918 | 1.40 |
| Carbon dioxide (CO₂) | 44.01 | 0.1889 | 0.846 | 1.29 |
| Water vapor (H₂O) | 18.02 | 0.4615 | 1.864 | 1.33 |
| Helium (He) | 4.003 | 2.0769 | 5.193 | 1.67 |
Putting it together綜合應用
Example範例 Interpolating the steam table蒸汽表插値 ›
Given: saturated water vapor at 55 °C. $h_g(50°\mathrm{C})=2592.1$ and $h_g(60°\mathrm{C})=2609.6$ kJ/kg.已知:55 °C 的飽和水蒸氣。$h_g(50°\mathrm{C})=2592.1$,$h_g(60°\mathrm{C})=2609.6$ kJ/kg。
Find: $h_g$ at 55 °C.求:55 °C 的 $h_g$。
Solution. 55 °C is halfway between the rows: $$h_g = 2592.1 + (2609.6-2592.1)\frac{55-50}{60-50} = 2600.9\ \tfrac{\text{kJ}}{\text{kg}}$$解:55 °C 在兩行正中間:$$h_g = 2592.1 + (2609.6-2592.1)\frac{55-50}{60-50} = 2600.9\ \tfrac{\text{kJ}}{\text{kg}}$$